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By John Thompson, Westek
Electronics Pty Ltd
Analytical testing of batteries is often
dismissed as an arcane science. The facts
are that with appropriate testing methods,
it is possible to determine battery
conditions for primary and secondary
batteries. For applications such as UPS
systems, testing of the battery bank can be
critically important. However there are also
production quality t, shelf life, and
effective charging/discharging issues under
real-life situations which call for testing
apparatus. This short note deals with a
series of battery testing apparatus
providing comprehensive battery parameters
information.
We distinguish between simple battery
testers used in the service shop
environment, which provide for some
charge/discharge testing in addition to
voltage output and those systems described
here that provide programmed discharge and
charging utilizing tailored protocols,
impedance testing as well as specific
application tests such as pulsed discharge
(mobile phone services for example). Load
tests obviously provide the ‘authoritative
answer’ but they are often a cumbersome
test—and require the taking out of service
of the battery being tested. Battery
impedance testing can be carried out without
the necessity of taking batteries out of
service.
The mechanisms responsible for battery
deterioration include loss of active
chemicals through corrosion processes and
evaporation, changes in the morphology of
active chemicals by way of dendritic growth
and crystal formations at the electrodes,
passivation of electrodes through the
build-up of resistive layers, shorting of
individual cells, and electrode cracking
such as can occur with Lithium polymers.
These various processes are often impossible
to assess by design engineers who are
incorporating primary or secondary batteries
into their designs—yet the effective battery
is often a critical parameter in customer
satisfaction with the product..
Battery testing ideally ought to provide
answers to questions including how much
charge is left, whether deterioration has
occurred, whether the battery meets
manufacturers specifications, the latter
being difficult to determine with the
exception, of course, of intelligent
batteries (which store original performance
data on an on-board chip that also records
recharge records, etc), and so forth. In
terms of predictive behaviour, impedance
measurements if taken consistently on a
particular battery or battery cell will
correlate with percentage remaining battery
life. The equivalent circuit below indicates
the elements making up the equivalent
circuit of a cell.
 Racid represents the
resistance of the electrolyte, Rmetal
is the
resistance of grids, posts and leads,
Relectr is the charge transfer resistance, C
is cell capacitance, and L is aggregate
inductance. The relative impedance change of
this circuit can be related to remaining
battery life. It might sound too good to be
true but with consistent multi-cell
measurements as a comparison base,
predictions on the basis of impedance
measurement become reliable. Thus an on-line
impedance monitoring regime on a string of
VSLA batteries in a large UPS installation
will provide significant benefits in terms
of ensuring reliable operation during power
failure periods.
The Basytech HPS series is optimised for a
power range of 100W to 30 kW. The modular
concept of the power amplifier makes the
system in a wide range configurable. The key
features include parallel connection of
channels with voltages up to 60V, impedance
measurements in frequency ranges from 10
micro Hz to 100 kHz; high speed control and
data acquisition to meet pulse profile
requirements, from 1 to 400 independent
channels per system operating under CC/CV
mode, RS232 or Ethernet communication,
optional environmental chamber temperature
control and extensive software options.
All data that is used for operation of the
system (i.e. battery parameters) and all
data measured with the system is stored in a
database system. The database system permits
the use the well known SQL (SQL-92) database
language. Usually the SQL language, commands
are automatically generated by the BaSyTest
Software.
The importance of a battery testing system
such as the Basytech HPS system as briefly
described above cannot be understated. In
state of health (SOH) determinations, for
example, it is generally accepted that this
be fixed at the number of charge/discharge
cycles required to reduce the battery energy
storage capacity to 80% of its rated value.
For mission-critical applications such as
communication hub UPS systems, determination
of SOH values for the individual batteries
may well have to be part of regular internal
maintenance procedures.
In manufacturing and distribution of
secondary battery-operated power tools,
quality assurance procedures may well
necessitate testing regimes of batteries
prior to distribution/sale of tools and such
testing may also have to be done in elevated
temperature environments. The Basytech HPS
system lends itself to control of
environmental chambers.
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